Giancoli 7th Edition textbook cover
Giancoli's Physics: Principles with Applications, 7th Edition
13
Temperature and Kinetic Theory
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13-1: Atomic Theory
13-2: Temperature and Thermometers
13-4: Thermal Expansion
13-5: Gas Laws; Absolute Temperature
13-6 and 13-7: Ideal Gas Law
13-8: Ideal Gas Law in Terms of Molecules; Avogadro's Number
13-9: Molecular Interpretation of Temperature
13-11: Real Gases; Phase Changes
13-12: Vapor Pressure and Humidity
13-13: Diffusion

Question by Giancoli, Douglas C., Physics: Principles with Applications, 7th Ed., ©2014, Reprinted by permission of Pearson Education Inc., New York.
Problem 39
Q

How many moles of water are there in 1.000 L at STP? How many molecules?

A
55.51 mol, 3.343×1025 molecules55.51 \textrm{ mol, } 3.343 \times 10^{25} \textrm{ molecules}
Giancoli 7th Edition, Chapter 13, Problem 39 solution video poster
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VIDEO TRANSCRIPT

This is Giancoli Answers with Mr. Dychko. The number of moles of water is going to be 1 liter times 1 times 10 to the minus 3 cubic meters per liter to convert this into cubic meters. And then multiplied by the density of water, and we assume it's fresh water, so, that's 1.000 times 10 to the 3 kilograms per cubic meter and then multiplied by 1 mole for every this many kilograms. So, we're basically, you know, we're multiplying by the reciprocal the molar mass. So, we have 1 mole for every 2 times 1.0079, that's the number of grams per grams per mole of hydrogen, and there's 2 hydrogens in a water molecule, it's H2O. And it's gram, so, that means that's why we have this times 10 to the minus 3 outside here to convert it to kilograms. And then plus the a single oxygen atom which is 15.9994. And this all works out to 55.51 moles. And the number of molecules will be the number of moles multiplied by Avogadro's number which is the number of molecules per mole. And so we take 55.50868 moles times 6.022 times 10 to the 23 molecules per mole. And we get 3.343 times 10 to the 25 molecules.

COMMENTS
By rjosephiv4 on Mon, 9/26/2022 - 1:42 AM

Why cant you use ideal gas law

By Mr. Dychko on Mon, 9/26/2022 - 2:24 PM

Hello rjosaphiv, thank you for the question. It makes sense that "STP" makes you think of gases, but as it turns out here - water is not a gas at Standard Temperature and Pressure. The standard temperature is 32 F32^\circ \textrm{ F}, 0 C0^\circ \textrm{ C} or 273 K273\textrm{ K}, at which point water is liquid, so our calculation uses the density of water as a liquid.
All the best,
Shaun

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